CUTOFF=n.nn

MOZYME calculations run faster when some NDDO interactions are ignored.  By default, all NDDO interactions are included between atoms separated by 12 Ångstroms or less, and all polarization functions between atoms separated by 30 Ångstroms or less.  For rough work, such as optimizing a structure that is far from a minimum, if CUTOFF=n.nn is used, then only point charge interactions beyond n.nn Ångstroms are used.  A suitable value for n.nn is 6.0.  This will give a large increase in speed.

If CUTOFF=6 is used, then GNORM=20 is recommended.  Once the geometry is optimized using GNORM=20, the CUTOFF should be increased (9 is a good value for general use) or removed, and GNORM reduced to, e.g., GNORM=10.

For the rare occasions when finer control is needed, use CUTOF1 and CUTOF2.

CUTOF1=n.nn

In MOZYME calculations, the cutoff distance for polarization functions is set by CUTOF1=n.nn. Beyond that distance, electrostatic interactions are considered only as point charges. At distances less than that given by CUTOF1, electrostatic interactions are represented by a point-charge and three polarization functions. Default: For systems of less than 30 atoms, CUTOF1 is 1000 Ångstroms; for systems of 30 or more atoms, CUTOF1 is 30 Ångstroms.

CUTOF2=n.nn

In MOZYME calculations, the cutoff distance for two-electron two center and one-electron two center integrals is set by CUTOF2=n.nn. Below that distance, the interaction between two atoms is represented by the exact NDDO approximation. Above that distance, one-electron integrals that depend on the overlap are ignored, and two-electron integrals are simplified. Instead of using all 100 two-electron integrals between two heavy atoms, only seven are used. These represent the terms <ss|ss>, <ss|sx>, <ss|sy>, <ss|sz>, <sx|ss>, <sy|ss>, and <sz|ss>.  At still greater distances, beyond CUTOF1, only the <ss|ss> term is used. Default: For systems of less than 30 atoms, CUTOF2 is 1000 Ångstroms; for systems of 30 or more atoms, CUTOF2 is 12 Ångstroms.